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北京时间2023年6月9日晚八点，iCANX Talks 第147期邀请到马德里康普顿斯大学Nazario Martín 教授分享分子级纳米石墨烯的合成与特性。更多精彩，敬请期待！

【嘉宾介绍】

Nazario Martín

Universidad Complutense

Bottom-up Molecular Nanographenes: Synthesis and Properties

【Abstract】

Chirality is an important and fascinating concept which has not been properly addressed in carbon nanoscience . We have previously reported the first inherently chiral bilayer nanographene with a helicene linker, both as the racemate and the M isomer . Helical bilayer nanographenes (HBNGs) are chiral π-extended aromatic compounds consisting in two π-π stacked hexa-benzocoronenes (HBC) joined by a helicene, thus resembling van der Waals layered 2D materials. Recently, we have synthesized and compared HBNG, HBNG and HBNG helical bilayers endowed with , and helicenes embedded in their structure, respectively. Interestingly, the helicene length defines the overlapping degree between the two HBCs (number of benzene rings involved in π-π interactions between the two layers), being of 26, 14 and 10 benzene rings, respectively, according to the X-ray analysis . More interesting, this overlapping also controls some of the properties.

手性是一个重要而迷人的概念，但在碳纳米科学中尚未得到适当的解决。我们之前报道了第一个固有的手性双层纳米石墨烯与螺旋烯连接，作为外消旋体和M异构体。螺旋双层纳米石墨烯(HBNGs)是一种手性π扩展芳香化合物，由两个π-π堆叠的六苯并冠烯(HBC)和螺旋烯连接而成，类似于范德华层状二维材料。最近，我们合成并比较了[9]HBNG、[10]HBNG和[11]HBNG螺旋双层结构中分别嵌入了[9]、[10]和[11]螺旋体。有趣的是，螺旋烯长度定义了两个HBC之间的重叠程度(两层之间π-π相互作用中涉及的苯环数量)，根据x射线分析，分别为26、14和10个苯环。更有趣的是，这种重叠也控制了一些属性。

【BIOGRAPHY】

NAZARIO MARTÍN is Full Professor of Organic Chemistry at UCM and vice-director of the IMDEA-Nanociencia Institute. He is Dr. h.c. by La Havana and Castilla La Mancha Universities and member of the Royal Academy of Sciences of Spain (RAC) and Royal Academy of Doctors of Spain. His research interests are focused on molecular and supramolecular chemistry of carbon nanostructures in the context of chirality, electron transfer and biomedical and photovoltaic applications. He has published over 600 peer reviewed papers and supervised 50 theses. He was Editor-in-Chief of J. Mater. Chem. (A, B and C. 2015-2019).

NAZARIO MARTÍN, 马德里康普顿斯大学有机化学教授，IMDEA纳米科学研究所副主任。他是哈瓦那大学和卡斯蒂亚拉曼查大学的荣誉博士，也是西班牙皇家科学院和西班牙皇家医生学会的成员。他的研究方向集中在手性、电子转移、生物医学和光伏应用背景下碳纳米结构的分子和超分子化学。发表同行评议论文600余篇，指导论文50余篇。他于2015-2019年担任J. Mater. Chem. (A, B and C)旗舰期刊的主编。

He held the Presidency of the Confederation of Scientific Societies of Spain (COSCE, 2015-19) and the Spanish Royal Society of Chemistry (2006-2012). He held the ERC Advanced Grant “Chirallcarbon” (2013-2019). Prof. Martín has been distinguished with several awards. Among them, the Gold Medal and Research Award of the RSEQ, 2012; Jaime I Award in basic research, 2012 Miguel Catalán Award CM, 2015; Alexander von Humboldt Award in 2013; Richard E. Smalley Award in 2013; and the EuChems lecture in 2012. More recently, he has been granted with the Synergy Grant-ERC project “Tomatto” (2021-2027) as well as the Spanish National Award in Chemistry “Enrique Moles” given by the Spanish Ministry for Science and Innovation (MICINN) in 2020.

他于2015-2019年担任西班牙科学学会联合会(COSCE)主席，2006-2012年担任西班牙皇家化学学会主席。2013-2019年他持有ERC高级资助“Chirallcarbon”。Martín教授曾多次获奖。其中，2012年获RSEQ金奖和研究奖；2012年获Jaime I基础研究奖，2015年获 Miguel Catalán Award CM；2013年获Alexander von Humboldt Award、Richard E. Smalley Award;以及2012年的EuChems lecture Award。最近，他获得了2021-2027年Synergy Grant-ERC项目“Tomatto”，并于2020年获得了西班牙科学与创新部(MICINN)颁发的西班牙国家化学奖“Enrique mole”。