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�п�Ժ��ӷ�Ӧ��ѧ�о��ֻ��Ҫ��չ��³ɹ��ѧ��Ŷ��Ե��׫д�� ڹ��׾��̽��F��HD��Ӧ�Ĺ��桷“ Probing the resonance potential in the F atom reaction with hydrogen deuteride with spectroscopic accuracy”��ڱ��ܳ��ҿ�ѧԺԺ��ϣ� PNAS 105��12662(2008)��ѡΪ��ڵķ��¡��Ǽ̽��֮��ʮһ��о��Ա�ڶ��PNAS��־�Ϸ��ġ��ҿ�ѧԺԺ��“ PNAS”��Ķ�ѧ�ƿ�ѧ��2007��Ӱ��Ϊ9.598��

��ѧ��Ӧ�еĹ��̬�Ƕ��ڷ�Ӧ��̬��ڹ��̬��Ļ�ѧ��Ӧ��쳣��У��ṩ��һ�ִ�ʵ��ֱ��̽�ⷴӦ��ֶΣ��о�Ҳ�ͳ�Ϊ�˶��ѧ��һ��Ҫ��⣬Ҳ��繫�ϵ��⡣��ǰ��ѧ��о��F+H2��Ӧ��ϵ�Ĺ��̬��ϸ��ʵ��о��״��ø߷ֱ�ķ�Ӧɢ��ʵ��̽�⵽��һ��ϵ�еķ�Ӧ��HF(v=2)��ǰ��ɢ�䣬��ҵõ��Ŷ��о�Ա��л��ǰ��ڵľ�ȷ��Ӷ��ѧ��ۼ��֤ʵ��о��2006��ġ��ѧ��־�ϣ� Science 311, 1440(2008)��⣬��ѧ��о�Ա��Ŷ��о�Ա�ֶ�F+H2��Ӧ��ϵ��HF(v=3)ǰ��ɢ��Ļ��ϸ�о��HF(v=3)ǰ��ɢ�䲢��һ��ϵ�ķ�Ӧ��̬��ģ��ڷ�Ӧ��ϵͨ��ʱ��ͨ��ɵġ��о��ڽ��·�� PNAS��־�ϣ� PNAS 105��6227(2008)��Ʒ��Զ�ܵ��ȵ��Ʋ⣺HF(v=3)ǰ��ɢ��ڷ�Ӧ��̬��ѧ��Ŷ��쵼��о��ʹ��Ƕ��һ��Ӧ�Ķ��ѧ��˸��⡣

��ǰ�˶�F+HD��Ӧ��о��֣��һ��Ӧ��ϵ��F+H2��Ӧ�зǳ��ԵĲ��˽�һ��ѧ��Ŷ��ԵȺ��չ�˶�F+HD��Ӧ�ĸ߾��ʵ��۵��о��ѧ��о��ƵĽ��—��ԭ��±�̬��ʶ̽��װ�ã��״��ڲ�ͬ��ײ��»��F+HD��>HF+D��Ӧȫ��̬�ֱ�ķ�Ӧ΢�ֽ��棬��ʵ��й۲⵽��0.3 kcal/mol�ķ�Ӧ��Χ�ڣ��÷�Ӧ��΢�ֽ��淢��˾��ҵı仯��ʵ��ǰ��δ�еĹ��׾��ȣ��ﵽ��cm—1�ľ��ȣ��һ��Ҫ��Ӧ�Ĺ��˶��ѧ�о��ҲΪ�߾��ȵ��о��ṩ�˲��ɶ�õ�ʵ��ݡ��ѧ��о��Ŷ��Ժ��Ͼ��ѧл��ǰ��ܾ�ȷ��F��H2��Ӧ�еĹ��̬�Ķ��ѧ��F��HD��Ӧ�еĹ��̬��롣Ϊ�ˣ��Ŷ��Ժ��Ŵ�ѧ��꿵��˺��¹��˸÷�Ӧ��һ��߾��ȵ��棬��ڸ��ϻ��ͬʱ��F��H2��F��HDʵ��߶��Ǻϵ��۽��Ӷ��״�ʵ��ͨ��Ӧ��ѧʵ��ֱ��ǰ��δ�еĹ��׾��̽�⻯ѧ��Ӧ��Ŀ�ꡣ��ɹ��Ǽ�2006��ڿ�ѧ��־�Ϸ��о��֮��߶��һ��ϵ̽��һ��Ҫͻ�ƣ��ڱ�� PNAS��־�ķ��ʽ��

��о��Ǳ��ܷ��е� PNAS��־��ѧ�о��д��Chemical Dynamics Special Feature��һ��֡��ѧ��д��ί��ҿ�ѧԺԺʿCrim��ڽ��ܱ����ʱָ��ڻ�ѧ��Ӧ��̬��ʵ��۲⻹��ۼ��㶼��зǳ��ս�ԣ��F+HD�о��չʾ��ڻ�ȡ��Ӧ��ȷ��̽��棬ʵ��ϵľ޴��

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��ҿ�ѧԺԺ�� PNAS��September 2, 2008 vol. 105 no. 35 12662-12666��Zefeng Ren, Li Che, Minghui Qiu, Xingan Wang, Wenrui Dong, Dongxu Dai, Xiuyan Wang, Xueming Yang, Zhigang Sun, Bina Fu, Soo-Y. Lee, Xin Xu, and Dong H. Zhang��

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